I've done my best to sweep the forum for similar issues, and in fact found at least one, but to my knowledge it yet to be solved.
Basically, I use PIE to enable box-shadow and border-radius capabilities in IE8. It works almost perfectly, but with two caveats (one major and one minor), unfortunately. I'll discuss the major one here:
I'm developing a site locally in WordPress (so I can't provide a live link, I'm afraid), but I'll do my best to submit code and screenshots to explain the situation. I've used CSS3 decorations and transitions to create a slide-down/slide-up menu (with sub-menu capabilities) which works perfectly in webkit browsers. I realize transitions is not gonna work in IE, and I've accepted that. The menu markup simply consists of an unordered list, like:
Code:
<ul class="menu">
<li id="menu-item-xx">
<ul class="sub-menu">...</ul>
</li>
</ul>
I use CSS3 transitions to simulate the slide-down/slide-up. With opacity (0 -> 1) for fade-in effect and height (0 -> 22px) for the slide-in-expansion. I've also applied a box-shadow to menus/sub menus (ul-elements) and rounded corners on the bottom with border-radius. The last two effects works great, even in IE8. My problem arises when leaving the hover-state (mouseout): The menu background remains on screen instead of hiding (opacity: 0).
I've tried experimenting with -pie-watch-ancestors (might have used it wrong) and looked into the whole fireEvent-technique (but according to some comments, I don't think that's it here). Right now I'm avoiding applying behavior on hover and moved it to the target element instead, as some suggested.
Instead of pasting all the code on here, I've created (and attempted to clean up) a jsfiddle:
http://jsfiddle.net/mbFVs/1/I know that won't help reproduce the problem, since PIE is not loading, but at least the markup and CSS can be fiddled with. Also, I am aware of other issues in IE8, as the sub-menu displaying immediately, but right now, this is my primary issue.
Below I've attached a couple of screenshots depicting the whole scenario.
Hope somebody can point me in the right direction

PS. I use selectivizr to enable some selector-power, which works as expected, and I've tried disabling that in debugging, so that can be ruled out as the bad guy.